Perfluoroalkylated Sulfoximines as Analogues of Togni Reagents: The Crucial Role of Fluorine Atoms for the Stability of Hypervalent Iodine Scaffolds
Abstract
Hypervalent iodine compounds are described with perfluoroalkyl chains and S-perfluoromethyl sulfoximines as ligands of the halogen. The influence of these groups on the stability of the cyclic structure is studied. The crucial role of the trifluoromethyl chain is clearly highlighted as an efficient ligand for the hypervalency. The structure and the reactivity of the new skeletons are discussed in detail. Show more
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https://doi.org/10.3929/ethz-b-000644984Publication status
publishedExternal links
Journal / series
European Journal of Organic ChemistryVolume
Pages / Article No.
Publisher
Wiley-VCHSubject
hypervalent compounds; fluorine; iodine; sulfoximine; trifluoromethylFunding
175680 - HYPervalent IodoSULfoximines as new perfluoroalkylating reagents (HYPISUL) (SNF)
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