Modulating Paratropicity in Heteroarene-Fused Expanded Pentalenes
dc.contributor.author
Jalife, Said
dc.contributor.author
Tsybizova, Alexandra
dc.contributor.author
Gershoni-Poranne, Renana
dc.contributor.author
Wu, Judy I.
dc.date.accessioned
2024-02-26T09:55:43Z
dc.date.available
2024-02-25T08:17:32Z
dc.date.available
2024-02-26T09:55:43Z
dc.date.issued
2024-02-16
dc.identifier.issn
1523-7060
dc.identifier.issn
1523-7052
dc.identifier.other
10.1021/acs.orglett.4c00188
en_US
dc.identifier.uri
http://hdl.handle.net/20.500.11850/661347
dc.description.abstract
Pentalenes are formally eight-pi-electron antiaromatic, but pi-expanded pentalenes can display varying levels of paratropicity depending on the choice of annelated (hetero)arenes and the geometry of pi-expansion (i.e., linear vs bent topologies) around the [4n] core. Here, we explain the effects of annelation on the paratropicity of pi-expanded pentalenes by relating the electronic structure of pentalenes to a pair of conjoined pentafulvenes.
en_US
dc.language.iso
en
en_US
dc.publisher
American Chemical Society
en_US
dc.title
Modulating Paratropicity in Heteroarene-Fused Expanded Pentalenes
en_US
dc.type
Journal Article
dc.date.published
2024-02-02
ethz.journal.title
Organic Letters
ethz.journal.volume
26
en_US
ethz.journal.issue
6
en_US
ethz.journal.abbreviated
Org. Lett.
ethz.pages.start
1293
en_US
ethz.pages.end
1298
en_US
ethz.identifier.wos
ethz.identifier.scopus
ethz.publication.status
published
en_US
ethz.date.deposited
2024-02-25T08:17:35Z
ethz.source
WOS
ethz.eth
yes
en_US
ethz.availability
Metadata only
en_US
ethz.rosetta.installDate
2024-02-26T09:55:44Z
ethz.rosetta.lastUpdated
2024-02-26T09:55:44Z
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true
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true
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Journal Article [128972]