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Date
2024-02-07Type
- Journal Article
ETH Bibliography
yes
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Abstract
Despite the appeal of organic redox systems as next-generation energy-storage media, achieving high cell voltages with electrolytes based on main-group elements typically comes at the cost of reduced long-term stabilities. In this Synpacts article, we summarize our recent finding that the introduction of phosphine oxide functionalities can unlock the ability of terthiophenes to serve as robust two-electron acceptors at extreme potentials. These investigations uncovered a fundamentally new class of multielectron redox systems, capable of expanding the cell potential range achievable with organic electrolytes without compromising stability. Show more
Publication status
publishedExternal links
Journal / series
SynlettVolume
Pages / Article No.
Publisher
ThiemeSubject
Redox chemistry; Main-group radicals; Energy storage; Electrochemistry; Terthiophenes; Phosphine oxidesOrganisational unit
09759 - Bezdek, Máté József / Bezdek, Máté József
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ETH Bibliography
yes
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