Probing the Nature of Surface Hydrides by Deuterium Quadrupolar Parameters: A Case Study on Silica-Supported Zirconium Hydrides
dc.contributor.author
Docherty, Scott R.
dc.contributor.author
Schärz, Philipp
dc.contributor.author
Gioffrè, Domenico
dc.contributor.author
Yakimov, Alexander
dc.contributor.author
Copéret, Christophe
dc.date.accessioned
2024-02-28T14:18:57Z
dc.date.available
2023-12-19T10:34:23Z
dc.date.available
2023-12-19T14:57:15Z
dc.date.available
2023-12-19T14:57:47Z
dc.date.available
2023-12-22T08:39:57Z
dc.date.available
2024-02-28T14:18:57Z
dc.date.issued
2024-01
dc.identifier.issn
0018-019X
dc.identifier.issn
1522-2675
dc.identifier.other
10.1002/hlca.202300173
en_US
dc.identifier.uri
http://hdl.handle.net/20.500.11850/648546
dc.identifier.doi
10.3929/ethz-b-000648546
dc.description.abstract
Supported metal hydrides are key reactive intermediates in various catalytic processes, such as hydrogenation and dehydrogenation, but are often challenging to characterize spectroscopically. Here, deuterium solid state nuclear magnetic resonance spectroscopy is used to understand the structure of the corresponding silica-supported zirconium hydrides after H/D exchange as an illustrative example of supported metal hydrides, which have been shown to display notable reactivity towards small molecules (e. g., CO₂ and N₂O) and to activate both C−H and C−C bonds, hence their use in to the conversion of hydrocarbons (alkanes, polyolefins etc.)
en_US
dc.format
application/pdf
en_US
dc.language.iso
en
en_US
dc.publisher
Wiley‐VHCA
dc.rights.uri
http://creativecommons.org/licenses/by-nc/4.0/
dc.subject
H/D exchange
en_US
dc.subject
hydrides
en_US
dc.subject
metal hydrides
en_US
dc.subject
solid-state NMR
en_US
dc.subject
solid-state structures
en_US
dc.title
Probing the Nature of Surface Hydrides by Deuterium Quadrupolar Parameters: A Case Study on Silica-Supported Zirconium Hydrides
en_US
dc.type
Journal Article
dc.rights.license
Creative Commons Attribution-NonCommercial 4.0 International
dc.date.published
2023-11-23
ethz.journal.title
Helvetica Chimica Acta
ethz.journal.volume
107
en_US
ethz.journal.issue
1
en_US
ethz.journal.abbreviated
Helv. Chim. Acta
ethz.pages.start
e202300173
en_US
ethz.size
9 p.
en_US
ethz.version.deposit
publishedVersion
en_US
ethz.grant
Molecular Approach to Heterogeneous Catalysis
en_US
ethz.grant
Molecular Approach and Understanding in Heterogeneous Catalysis
en_US
ethz.identifier.wos
ethz.identifier.scopus
ethz.publication.status
published
en_US
ethz.leitzahl
ETH Zürich::00002 - ETH Zürich::00012 - Lehre und Forschung::00007 - Departemente::02020 - Dep. Chemie und Angewandte Biowiss. / Dep. of Chemistry and Applied Biosc.::02513 - Laboratorium für Anorganische Chemie / Laboratory of Inorganic Chemistry::03872 - Copéret, Christophe / Copéret, Christophe
en_US
ethz.leitzahl.certified
ETH Zürich::00002 - ETH Zürich::00012 - Lehre und Forschung::00007 - Departemente::02020 - Dep. Chemie und Angewandte Biowiss. / Dep. of Chemistry and Applied Biosc.::02513 - Laboratorium für Anorganische Chemie / Laboratory of Inorganic Chemistry::03872 - Copéret, Christophe / Copéret, Christophe
ethz.grant.agreementno
169134
ethz.grant.agreementno
192050
ethz.grant.fundername
SNF
ethz.grant.fundername
SNF
ethz.grant.funderDoi
10.13039/501100001711
ethz.grant.funderDoi
10.13039/501100001711
ethz.grant.program
Projekte MINT
ethz.grant.program
Exzellenzbeitrag in MINT
ethz.date.deposited
2023-12-19T10:34:33Z
ethz.source
WOS
ethz.eth
yes
en_US
ethz.availability
Open access
en_US
ethz.rosetta.installDate
2024-02-28T14:18:58Z
ethz.rosetta.lastUpdated
2024-02-28T14:18:58Z
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true
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true
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